Marvel's Ultimate Spider-Man

Season 3, Episode 9

Episode Title: New Warriors

Air Date: 2014-10-14

Overview:

Now that the other young heroes have been assembled, Spider-Man must lead them into defending the Tri-Carrier from the Thunderbolts (consisting of Taskmaster, Vulture, and Cloak and Dagger) where they managed to spring Green Goblin, Doctor Octopus, Beetle, and Scorpion from their cells.